Crystal structure of tetrakis(acetylacetonato)dichloridodi-μ3-methanolato-tetra-μ2-methanolato-tetrairon(III)
نویسندگان
چکیده
The title complex, [Fe4(C5H7O2)4(CH3O)6Cl2] or [Fe4(acac)4(μ2-OMe)4(μ3-OMe)2Cl2] (acac = acetyl-acetonate), crystallizes in the ortho-rhom-bic Pbca space group with one half of the mol-ecule per asymmetric unit, the other half being completed by inversion symmetry. The core structure consists of a face-sharing double pseudo-cubane entity with two opposite corners missing. Weak C-H⋯Cl inter-molecular inter-actions result in a two-dimensional layered structure parallel to the ac plane.
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عنوان ژورنال:
دوره 71 شماره
صفحات -
تاریخ انتشار 2015